N-{(E)-4-[(E)-(Dodecylimino)methyl]benzylidene}dodecan-1-imine
نویسندگان
چکیده
The title compound, C(32)H(56)N(2), was synthesized by the reaction of terephthalaldehyde and dodecan-1-amine. The imines adopt trans conformations, with the two halves of the mol-ecule related to each other by a centre of symmetry.
منابع مشابه
1-(Thiophen-2-yl)-N-(4-{(E)-[(thiophen-2-yl)methyl]iminomethyl}benzylidene)methanamine
The title compound C(18)H(16)N(2)S(2), crystallizes with two independent half-mol-ecules in the asymmetric unit, in one of which the thio-phene rings are disordered in a 0.67:0.33 ratio. Each independent mol-ecule lies across a crystallographic centre of symmetry. The dihedral angle between central (half) benzene ring and the thiophene ring is 11.82°.
متن کامل(E,E)-N′-{4-[(2-Benzoylhydrazin-1-ylidene)methyl]benzylidene}benzohydrazide
In the title compound, C(22)H(18)N(4)O(2), the mol-ecules lie across an inversion centre. The dihedral angle between the mean planes of the central and terminal benzene rings is 66.03 (2)°. The mol-ecule displays trans and anti conformations about the C=N and N-N bonds, respectively. In the crystal, N-H⋯O hydrogen bonds, with the O atoms of C=O groups acting as acceptors, link the mol-ecules in...
متن کاملCrystal structure of (E)-4-methoxy-2-{[(5-methylpyridin-2-yl)imino]methyl}phenol
The mol-ecule of the title Schiff base compound, C14H14N2O2, displays an E conformation with respect the imine C=N double bond. The mol-ecule is approximately planar, with the dihedral angle formed by the planes of the pyridine and benzene rings being 5.72 (6)°. There is an intra-molecular hydrogen bond involving the phenolic H and imine N atoms.
متن کامل(SP-4-2)-Chlorido{N-[2-(diphenylphosphanyl)benzylidene]benzylamine-κ2 P,N}(methyl)palladium(II)
In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.
متن کامل3-[(E)-(Benzyliminiumyl)methyl]-6,8-dichloro-2H-chromen-4-olate
In the title compound, C17H13Cl2NO2, the H atom of the -OH group is transferred to the N atom of the imine, forming a zwitterion. Thus, there is a intra-molecular O⋯H-N, rather than O-H⋯N, hydrogen bond, which forms a six-membered ring.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008